IR Spectra: Tricks for. Identifying the 5 Zones. It's easier than you think! ☺. Introduction: The light our eyes see is a small part of a broad spectr...
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IR Spectra: Tricks for Identifying the 5 Zones It’s easier than you think!
Introduction: The light our eyes see is a small part of a broad spectrum of electromagnetic radiation. On the immediate high energy side of the visible spectrum is the ultraviolet, and on the low energy side is the infrared. The portion of the infrared region is used for analysis of organic compounds.
Why is it useful? Infrared (IR) spectroscopy is one of the most common spectroscopic techniques used by organic and inorganic chemists. Simply, it is the absorption measurement of different IR frequencies by a sample positioned in the path of an IR beam. The main goal of IR spectroscopic analysis is to determine the chemical functional groups in the sample. Different functional groups absorb characteristic frequencies of IR radiation.
Basically: We use the IR Spectrum to identify Functional Groups that are present within a molecule. This is important because knowing the functional groups present brings us closer to identifying an unknown substance and molecule.
Infrared Spectrum: is the plot of photon energy (x axis) versus the amount of photons (y axis) • X axis: the stretching frequency • Y axis: the amount of photons absorbed IR Spectrum looks like this:
The IR Spectrum is divided into 5 Zones and a Fingerprint Region. As Chemistry 14C students we do not need to know how to interpret the Fingerprint region.
FIVE ZONES •
Each zone has a characteristic frequency and in each zone specific bonds have very specific peak intensities. Looking at the peak determines what functional group is present.
Characteristic Stretching Frequencies: The Five Zones (Table) Stretching Frequency (cm-1)
Bond
ZONE 1: 3700-3200 cm Alcohol O-H Alkyne ≡C-H Amine or Amide N-H
Intensity and Shape -1
3650-3200 cm-1 3340-3250 3500-3200
Usually strong and broad Usually strong and sharp Medium; often broad
ZONE 2: 3200-2700 cm -1 Aryl or Vinyl sp^2 C-H Alkyl sp^3 C-H Aldehyde Carboxylic Acid O-H
3100-3000 2960-2850 ~2900 and ~2700 3000-25000
Variable Variable Medium; two peaks Usually strong; very broad
ZONE 3: 2300-2000 cm -1 Alkyne C≡C Nitrile C≡N
2260-2000 2260-2220
Variable and sharp Variable and sharp
ZONE 4: 1850-1650 cm -1 Ketone C=O Ester C=O Aldehyde C=O Carboxylic Acid C=O Amide C=O
1750-1705 1750-1735 1740-1720 1725-1700 1690-1650
Strong Strong Strong Strong Strong
ZONE 5: 1680-1450 cm -1 Alkene C=C Benzene Ring C=C
1680-1620 ~1600 and ~1500
Variable ~1600 often has 2 peaks
Attention: The functional group BOLDED are the ones that appear in more than one zone. They must be present in all characteristic zones to exist.
Functional Groups : Here’s a quick recap of some functional groups in case you forgot.
Ketone
Ester
Aldehyde
Carboxylic Acid
Amide
Amine
Tricks for Remembering the FUNCTIONAL GROUPS A Ketone is CoCy (Cocky) KETONE COC Ester is a cooc (Cook) ESTER COOC Al Cohs (A man named Al Coughs) Aldehyde COH
Tricks for Identifying the Zones
Practice Problem: Using what you have just learned. Decide which of the following 5 molecules the IR Spectrum below depicts.
Solution: You can solve this problem by process of elimination. 1. By looking at the IR Spectrum you can eliminate all molecules with an alcohol in it (cyclobutanol and 2-methyl-2-propen-1-ol). This is because the IR spectrum does not show an alcohol present. (Remember: You need a broad peak at about 3300. Hint: Alcohol peak looks like a tongue.) 2. Now you have three choices left. 2-butanone has a ketone present in the molecule. (Remember: A ketone is a Carbon double bonded to an oxygen. The carbon is bonded to two other Carbons). Ethyl Vinyl Ether has an ether present in the molecule (An ether is one functional group that is not identified on within the 5 zones so move on to the next molecule). 2-methylpropanal has an aldehyde in its molecule. (Remember: An aldehyde is a carbon double bonded to oxygen. The carbon is bonded to a carbon and hydrogen). 3. So by looking at the IR Spectrum above, do you see a ketone or an aldehyde present? We can immediately tell that the molecule portrayed by the IR spectrum must be the last molecule (2-methylpropanal) because the IR spectrum has a peak in Zone 2 at 2700 and 2900. This signifies that an Aldehyde is present. Answer: 2-methylpropanal
The IR spectrums for the remaining choices would look like this:
Sources: Dr. Hardinger’s Chem 14C Lecture Supplement http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/Spectrpy/InfraRed/infrared.htm http://www.prenhall.com/settle/chapters/ch15.pdf Images: All images of Functional Groups (Ketone, Ester, Aldehyde, Carboxylic Acid, Amine, Amide) were taken from Wikipedia. http://en.wikipedia.org/wiki/Functional_group http://toeholds.files.wordpress.com/2010/09/ir-illustrated.pdf Spectral Graphs: (http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/Spectrpy/InfraRed/infrared.htm)
