MSDS No.: C265505 Issue Date: 12/07/04
MATERIAL SAFETY DATA SHEET Section 1: CHEMICAL IDENTITY AND USE Product Name: CYPERMETHRIN 5 + CHLORPYRIFOS 50% EC Active ingredient: Cypermethrin, Chlorpyrifos Chemical Classification: Synthetic pyrethroid (cypermethrin), Organophosphorus (chlorpyrifos) Formula: (cypermethrin) C22H19Cl2 NO3 , (chlorpyrifos) C9H11Cl3NO3PS Chemical Name: Cyano (3-phenoxyphenyl)methyl 3-(2,2-dichloroethylenenyl)-2,2dimethyl=cyclopropanecarboxylate. (cypermethrin) O,O -diethyl O-(3,5,6-trichloro-2-pyridinyl) phosphorothioate. (chlorpyrifos) CAS No.: (cypermethrin) [52315-07-8], (chlorpyrifos) [2921-88-2] USE of product :Insecticide. Molecular weight: 416.3 (cypermethrin) 350.6 (chlorpyrifos)
Section 2: COMPOSITION /INFORMATION ON INGREDIENTS Ingredients CAS No. % EU number PEL/TLV EU class 1. Cypermethrin [52315-07-8] 5.00 DNA DNA DNA 2. Chlorpyrifos [2921-88-2] 50.0 2. Other ingredients 45.00
NTP/IARC/OSHA DNA
Section 3: HEALTH HAZARD INFORMATION Acute exposure effect : High vapour concentration may cause headache, necrosis and irritation to mucous membrane. Ingestion can be fatal. STEL (ACGIH)
DNA
IDLH
DNA
Section 4: FIRST AID MEASURES If poisoning occurs, contact a doctor or Poison Information Center. Eyes : Rinse eyes well with water for at least 15 minutes. Skin : Remove any contaminated clothing, wash skin thoroughly. Inhalation : Remove from source of contaminated to open space/fresh air. Ingestion : Induce vomiting by tickling back of throat. Repeat it until the vomitus is clear. Do not induce vomiting if the patient is unconscious. Antidote : Treat symptomatically.
Product Name: CYPERMETHRIN 5% + CHLORPYRIFOS 50% EC
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MSDS No.: C265505 Issue Date: 12/07/04 Section 5: FIRE AND EXPLOSION HAZARD Flash point: >24.5 0 C Explosion sensitivity to static Electricity: Yes Explosive Material: No Corrosive Material: No Oxidizer: No Flammability LEL % V: Not pertinent UEL % V: Not pertinent Organic Peroxide: No
Autoignition temperature: DNA Explosion sensitivity to Impact: No Flammable Material: No Pyrophoric Material: No Hazardous polymerization: No Fire fighting media: Foam, dry agent Special procedure: No
Section 6:ACCIDENTAL RELEASE MEASURES AND DISPOSAL CONSIDERATIONS Spills: Steps to be taken: Stop leak, if safe to do so. Contain spillage. Absorb in sawdust or sand or disposal. Eliminate sources of ignition. Use personal protective equipment. Stay upwind. Cordon off the area. Waste Disposal method: Local regulations should be adhered to. Incineration in controlled furnace. Destroy the empty containers in a safe and authorized place. If burnt avoid inhalation of smoke (if burning permitted). Never re-use empty packs. Section 7: HANDLING AND STORAGE PRECAUTION Store in the closed, original container in a well -ventilated area a. Do not store for long periods in direct sunlight. Keep in cool place. Section 8: PERSONAL PROTECTIVE Engineering measures : Ensure adequate ventilation, especially in confined areas. Personal protective equipment: Respiratory protection: respirator with P2 filter. Eye protection: safety glasses, face-shield. Hand protection: protective gloves. Skin and body protection: protective suit. Hygiene measures: Wash hands and face before breaks and immediately after handling the product. Keep away from food, drink and animal feeding stuffs. When using, do not eat, drink or smoke. Avoid contact with skin. Section 9: PHYSICAL AND CHEMICAL INFORMATION Appearance: Brown coloured viscous liquid pH: 6.8. Acidity as H2SO4: 0.02% Density: 1.17-1.18 g/ml Emulsion stability: no creaming at top and bottom Section 10: REACTIVITY DATA Chemical stability: Stable at normal condition. Incompatible with other material: Strong oxidizers Reactivity: None Hazardous reaction product: None Product Name: CYPERMETHRIN 5% + CHLORPYRIFOS 50% EC
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MSDS No.: C265505 Issue Date: 12/07/04 Section 11: TOXICITY INFORMATION Oral : 7180 mg/kg (rat) Dermal : > 4920 mg/kg (rat) Inhalation : > 2.50 mg/a.i./l (4 hr) (rat). Eye contact : Slight eye irritant (rabbit) Skin contact : Slight skin irritant (rabbit) Skin sensitization : A weak sensitizer (guinea pig) Mutagenic potential : Non mutagenic Teratogenicity potential : Non teratogenic Carcinogenicity : Non carcinogenic Acceptable Daily Intake (ADI) : 0.05 mg/kg b.w. Section 12: ECOLOGICAL INFORMATION Bees : 24 h LD 50 (oral) 0.035 g/bee;(topical) 0.02 g/bee. Birds : Acute oral LD 50 for mallard duck: > 10000 mg/kg, chickens >2000 mg/kg. Fish : LC 50 (96 hr) for carp : 0.61mg/l, Rainbow trout : 0.69 mg/l . Section 13: TRANSPORT INFORMATION Type of chemical: Pyrethroid Pesticide, Liquid, Toxic, flash point not less than 23 degree Celsius. IMCO class: 6.1 UN Number: 3351 IMDG Page Code: 6220 EMS No. : 6.1-02 MFAG : 510 Section 14: PACKING INFORMATION Packed in 250 ml, 500 ml, 1 lt. aluminium bottles. Packing group-III.
Section 15: DISCLAIMER Information contained in this material safety data sheet is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. It is up to the User/Distributor to ensure that the information contained in the material safety data sheet is relevant to the product manufactured/handled or sold by him as the case may be, Sulphur Mills Ltd. makes no warranties, expressed or implied, in respect of the adequacy of this document for any particular purpose.
Product Name: CYPERMETHRIN 5% + CHLORPYRIFOS 50% EC
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