NASA TECHNICAL NOTE NASATN D-8508

NASA TECHNICAL NOTE O! Z I--Z NASATN D-8508 A NICKEL-CADMIUM BATTERY RECONDITIONING CIRCUIT Roy Lanier George C. Marshall Space Flight Center...

4 downloads 468 Views 850KB Size
https://ntrs.nasa.gov/search.jsp?R=19770018686 2018-02-12T02:28:53+00:00Z

NASA

TECHNICAL

NASATN D-8508

NOTE

O !

Z I--

Z

A NICKEL-CADMIUM

BATTERY

RECONDITIONING

CIRCUIT

Roy Lanier George C. Marshall Marshall NATIONAL

Space Flight

Space Flight

AERONAUTICS

AND

SPACE

Center

Center, Ala. ADMINISTRATION



35812 WASHINGTON,

O. C.



JUNE 1977

1.

REPORT

NO.

2.

GOVERNMENT

ACCESSION

NO.

3.

RECIPIENT'S

CATALOG

5.

REPORT

DATE

June

1977

NO,

NASA TN D-8508 4.

TITLE

AND

SUBTITLE

_A Nickel-Cadmium

Battery

Reconditioning

6.

Circuit

7. AUTHOR(S) Roy Lanier 9. PERFORMING ORGANIZATION NAMEANDADDRESS George

C.

Marshall

Marshall Space

Space

Flight

Flight

Center,

SPONSORING

National

AGENCY

NAME

Aeronautics

Washington,

AND

1.

CONTRACT

OR

GRANT

NO.

TYPE

OF

REPOR',

&

PERIOD

COVERED

ADDRESS

and Space

D.C.

CODE

35812 3.

2.

ORGANIZATION

8.PERFORMING ORGANIZATION REPORt# M-221 10. woRKUNIT NO.

Center

Alabama

PERFORMING

Administration

Technica] 14.

20547

Note

SPONSORING

AGENCY

CODE

15. SUPPLEMENTARY NOTES Prepared 6,

by Electronics

The

that

circuit

battery

_'ground-type" recondition

Laboratory,

high

with

(greater

(100

voltage

than

even

This report to its use.

voltage

after

Science

and

and

small

is simple

assembly,

yet

to 150 Vdc) systems

have

counterpart,

and

battery

in low

orbit

this

circuit

nameplate

over

20 000

Earth

that can

power

returns

a greater

and

simulated

orbital

Unclassified

(o_

thLI

report_

for

used to show

of its

new battery

a 4 year

period.

The

implications

reconditioning the

are

than

expected

its

life

in

that low

of a

be up to 5 years.

18.

CLASSIF.

when results

90 percent

a typical

cycles

techniques,

WORDS

SECURITY

circuit These

than

in a

of a complete

circuit and makes recommendations (22 to 36 Vdc) power systems and

for battery

circuit

to be included

advantage

Oll the given.

follows

is discussed.

need

these

the

to greater

capacity)

systems

using

enough

provides

DISTRIBUTION

STAR

19.

Engineering

Test results batteries are

addresses applications of the Its application in low voltage

voltage

KE_

paper

control

reconditioned curve

high

in this

battery reconditioning discharge. two 24 cell, 20 A-h nickel-cadmium

capacity

degradation

relative

presented

charge/power

a battery

original

17.

Control

ABSTRACT

typical

the

and

20.

SECURITY

CLASSIF.

(of

thL.

STATEMENT

Category

44

page)

21.

Unclassified *For

sale

NO.

OF

PAGES

29 by

the

National

Technical

Information

Service,

22.

PRICE

$4. O0 Springfield,

Virginia

22161.

TABLEOF CONTENTS

Page SUMMARY

.......................................

INTRODUC

TION

BACKGROUND

................................... ....................................

SYSTEM

DESCRIPTION

..............................

CIRCUIT

DESCRIPTION

..............

CIRCUIT

APPLICATION

..............................

TEST

RESULTS

OTHER

Capacity

Battery

Voltage Results

APPLICATIONS

CONC LUSlON REFERENCES

................

8 i0

....................................

Battery Other

1

13 13

.............................. Characteristics

....................

................................

15 15

..............................

22

.....................................

23

....................................

24

iii

LIST OF ILLUSTRATIONS

Title

Figure I.

,

3.

,

Battery Cyclic

life

ATM Life

capacity test

test

Simplified

.

Battery

Power

configuration flight

V for

System

.

Battery

mismatch

Typical

end

.....

3

...................

circuit

circuit

output

Energy extraction from battery reconditioning .............................. 2 voltage

battery

........................

reconditioning

Battery

a 20 A-h

......................

reconditioning

,

I0.

26.4

capacities

Electrical

.

.

above

Page

discharge

Ii.

Battery

2 cell

voltages

12.

Battery

1 recharge

17

................

18

before

and

after 19

at end

fraction

12

_irst

.................

voltage

..............................

.....

16

characteristics

of discharge

characteristic

2 during

profile

reconditioning

11

..............

of discharge

anomaly

iv

...........

...............

20 21

A NICKEL-CADMIUM BATTERY RECONDITIONING CIRCUIT SUMMARY

The

degradation

cadmium

battery,

in space

electrical

of the

sometimes power

battery

at some

minimum

for bus

regulation

for

low voltage

sense

the

percentage

1.0

to 1.1

upon

parameters

reconditioning,

a predetermined battery has

and

The

The

voltage

and

temporary.

for

a load

flight.

on the

for this

a battery

enhancement

obtained

in this

a battery

for

loading

the

has

in the

past

reconditioning, the

bus,

battery

manner

has

typically dependence

graphically.

discharging

from

cycling,

voltage,

degradation

process

the

and

by individually

battery

and discharging

required

time

is demonstrated ground

Flight

of removing

resistor,

life

in the

by an automatic

with

voltage

of completely

done required

space

consisted

with

consists

been

equipment

complex

typically

battery

has

cycle

stored

is normally

at a particular The

is a problem

energy

shut-down

because,

available

and

which

time,

cells.

bulky

energy

significantly.

of the

voltage

system

occurs

of a nickel-

_' or "fading,"

on use

A minimum

problem

battery

decreases

effect

depend

and to preclude The

characteristic

TTmemory that

voltage.

users

of total

V/cell,

discharge

called systems

device.

environmental

Battery

voltage

loading

to 0.9

been

been

when the

to 1.0

shown

too

used, entire

V/cell.

to be minimal

INTRODUCTION

(Ni-Cd)

Nickel-cadmium storing tion,

electrical which

space cells

connected

store

These in series,

batteries. energy

use

later

are treated with care, where DOD is defined

vehicles

batteries, may

supplied orbit.

have

been

designed

discharge-charge typically

by a solar

limiting as:

the

primary

for

alone array)

temperature

the

with

or in parallel

the batteries

reliable,

during long life and

means

low Earth since

constructed

applications,

To assure

the

cycles,

be operated

In all of the

(usually in the

on space

repeated

exploration.

identical for

energy

require

batteries

depth

orbit

opera-

inception

of

18 to 30 Ni-Cd with

are

of

other

called

nearly

upon

to

a portion

of the

orbit

operation,

the

batteries

of discharge

(DOD)

DOD=

(A-h

out/A-h

rated)

x 100%

where

DOD

= batter5

A-h out = the A-h

rated

= the

In spite

of this,

Ni-Cd

degrade

with time

depth

oi discharge

ampere

hours

battery

rated

batteries

as shown

discharged capacity.

voltage

in Figure

capacity

characteristics

typically

1.

The battery voltage degradation, sometimes

called "memory"

or "fading,"

depends on several parameters

such as charge characteristics, temperature,

and DOD.

because the battery is used as a voltage source,

It causes a problem

and if the energy is not available at or above some cannot use this energy. V/cell. the

In addition,

potential

on one

The reversible

process,

and the

called

discharged been

battery

generally

cell been

reliability, this

in a space is capable battery. circuit, ures. only

2

some

in a Ni-Cd

considered valid.

approximately of providing

the the

are This size

each

report

of two 20 A-h

necessary

operations

However, heavy

A recent

presents for

a ground

reconditioning operation,

of Ni-Cd and

flight

batteries

reconditioning

report

need

that cells

is com-

and flight

has use

[1] can

has

discharging

this

where

recognized be packaged and

a Ni-Cd

as the battery certain battery

no longer

need

state

of a battery

reconditioning

The circuit reliability can be of the same order and the circuit can be designed to protect against Thus,

for

a circuit or larger

a

Reconditioning loading

network.

at a premium.

is largely

in the battery

of time.

and/or

reversing

cells.

to its original

by individually bulky,

risks

these battery

cell

period

resistor

too complex,

and space

as still

whereby

and

level

damaging

can be restored

predetermined

a relay

this

degradation

on the ground

through

below and

characteristic

performed

weight,

limitation

voltages

in a battery

"reconditioning" for

voltage the system

acceptable voltage is usually 1.0 to I. 1

at cell cells

characteristic

historically each

operation or more

voltage

by a process pletely

The minimum

minimum

charging fail-

be considered

not be considered

as a

140

]

120

>-

100

5 <

oOc

Q.

< {D t_

80

UJ

I< at" IZ I.IJ

60

o nr" 0.

40

20

0

!

0

Figure

2

i.

Battery

I

4

capacity

I

6 THOUSANDS above

26.4

I

8 OF ORBITS V for

a 20

A-h

I

1

10

12

battery.

superficial enhancement without

discharge at best.

bulky

equipment,

operations, life

to only 0.9 to 1.0 V/cell which provides a brief voltage Reconditioning of batteries in space can be accomplished

using

operations

this

and circuit.

in space

presented to provide and reserve capacity

to the

degree

previously

Electrical

should

realize

power

available

syster_s

a significant

reconditioning assuring throughout the mission.

designed

advantage

adequate

only

for

using

voltage

in ground the

long circuit

characteristics

BACKGROUND

A Charger/Battery/Regulator two CBRM'

s in October

Telescope Part four

Mount

Module

1972

(ATM)

to establish

batteries

during

No. 40M26202, Serial numbers 20 A-h Ni-Cd sealed cells with

signal

electrodes

overcharge

were

in the The

The

charge

15 A to a temperature in a tapering

electrode. typically

for

on the

compensated

voltage.

current,

DOD averaged Recharge

in/A-h

upcoming

The

fraction

A-h A-h

heat

on

Apollo batteries,

was and

to minimize removal.

58 and limited

voltage

is defined

The

battery

were

25 percent,

was

then

terminated the

35 min, mode

recharge

of up to

held

constant,

by the fraction

signal was

as:

(i)

out)

where

RF

of the radiative

charge

initiated

Skylab

assembled from twentysignal electrodes. The

of a current

until

was

mission.

and

batteries

test

of the

_ere

passive

consisted

to 1.10.

RF = (A-h

cycles

charge

the

termination

used

regime

The battery 1.05

charge

life

capabilities

80 and 84, recombination

which

charge-discharge

respectively. resulting

used

application

(CBRM)

the

= the battery

recharge

fraction

in

= the

ampere

hours

charged

out

= the

ampere

hours

discharged.

Battery temperatures were maintained between5°C and 15°C by controlling the CBRM radiative view factor to a cold plate in the vacuum environment of the test. All of these factors were consistent with expected Skylab flight conditions. The test ran for approximately 7 months (3000 orbits) with expected results prior to the Skylab launch. The Skylablaunch was marred by the failure and loss of a heat shield on the Orbital Workshop (OWS), which caused the loss of one of two solar wings on the

OWS,

deployed heat

and

with

shield

the

loss

in a direction

This

phase

of the return

to have became

capacity it was

a test

loss with

known

the battery

The

recharging

limitation a ground

the

cells

because

of the

large

problem

indicateda

test

as

subject

to meet

a test

bed.

of this

a tried This

Skylab

hardware

procedure

complex

equipment a battery

The

for

need

has

been

circuit

reversal

and

developed

and the

to correct

most

tested

test

2,

However, effects,

of the space

it.

The

results

the

and

useable

for

flight Skylab

applicable using

a

the

discharging

its damaging

method

and

imme-

in Figure

to implement

developed

were

test

to restore

proposed

reconditioning

entire

unsuccessful.

restore

not been

required

life

of completely

would had

the

and the

a method

Efforts were

the

During

ATlvl batteries

as shown

procedure

procedure

with for

The

and,

experienced.

need this

simulated

cell

power

to define

was

against

using

battery.

A solution

of the

arrays

OWS living

operation

the

the

solar

of the

capacity.

attempt

was

However,

ATM

OWS problems,

conditions,

and

wing

of 15 ° to 30°C. supplied

of useable

was

system

of the

operating

reconditioning

protecting

of the

system

capacity

the

capacity

power correction

anomaly

that

of power

This

later.

and the overheating

temperature

to evaluate

of usable

cells,

ATM

wing.

weeks

vehicle

and

10 to 12 A-h

bed

several

days

normal

only

OWS solar

Sun to prevent

of a crew,

to near

anomaly.

comparable

the

balance the

other

of the

in several

mission

subsequent

flight

crew

energy

arrival

discovered this

of the orientation

resulted

After

diately

the

assistance required

at or near

vehicle.

to deploy

40 ° to 60 ° from

quarters. batteries this

a failure

to flight. CBRM

obtained

are

life the

report.

SYSTEM DESCRI PTION

The considered

block typical

It is characterized

diagram

of the

of systems by multiple

ATM

in which parallel

Electrical

Power

a reconditioning energy

System circuit

storage/power

in Figure would

3 is

be useful.

processing

stages

5

t_

o.

0

_o

CO

E _0

°..._

>_3 rr_: 0 "I"

rr 0

o rIJ

o 2

Z

.,_

_o

o

o

o

"r

_

_-

0

_q o O0

_

t/

J

°..._

_t

N

C r CO

SHnOH

6

- 3 _I3dlAIV

" AJ. IDVclVO

AB:_IIIVB

a 0 ._1

I I

o

O

\

0 .J

i

0

0 Z ..1

r-i

CD

ulJ qpw

I---

m_

rr

rn

(.9

_4 _

_n "1-

.-I _.1

_Z

_o

0

._I I_-

0 O9

_-

_

and multicell capability

Ni-Cd to isolate

energy

sharing

those

which

during

the

current,

ATM

batteries

that

were

storage.

The

reconditioning have

and

the

from

system

and

been

also

to assure

recently

electrode

has

the

proper

reconditioned

portion

of the The

sharing

the

solar sensed

voltage,

and

without

orbit,

and

batteries were protected the battery if its voltage

solar

array

current

the

solar

discharged the

output

approximately

from cell fell below

charger

voltage,

collapsing

shared

to assure

by the

battery

the battery

regulators

circuit

arrays

charger

charging

the loads.

load

from The

battery

"night"

each battery. The which disconnected

orbit.

signal

proper

the

charged

of the

to supply

on a signal

for

batteries

to assure

During

energy

batteries

portion

temperature

regulator

for

not.

"day"

voltage

array. the

the

between

have

The

and

batteries

through load

equal

based DOD in

reversal by a circuit 26.4 V ( 1.1 V/cell).

The lifetest configuration being used as a test bed for the reconditioning circuit discussed herein consists of two of the para]]el elements from the ATM Electrical Power

System

as shown in Figure 4.

CIRCUIT DESCRIPTION

A circuit objectives.

The

in the battery results

requirements

are

that

it must

completely

discharge

not allow

the

polarity

of any

to be reversed.

it must

the

later

to restore

or greater

of its

will

requirements.

useable

capacity

circuit

It should

be very

probably

fully

automated,

practical

time.

Cost

that

reduced

number

capacity

for

small

result

some

key

and should

from

This

complete

the

required will

far

desired will

time

size.

the

every

than

0.5

for

reliable

cost

of the

a recon-

desirable

as practical. be easy

reconditioning replacing

V/cell

and

be generally

of having

Test

greater

constraints

It should

cell

90 percent

objectives

is not a key

between

as a result exceed

and

and

25 percent

on system

the but

to less

is typically

that

to the battery

extending

mission

The

requirements

to approximately

be as simple

be minimized,

cell

discharge

objectives

should

several

capacity

depending

should

compared

meet

that

capacity.

circuit

of batteries

a given

shown useable

somewhat,

However, The

must

of the battery.

vary

be described.

savings

have

the battery

initia]

nameplate

ditioning may

a battery

to be discussed

is adequate than

and

to recondition

in the

feature

least

because

batteries a greater

to use, the

or the useable

reconditioning

circuit.

o0

a o _I

I

L'o

/

0 ._I

\

O 0 ,_J

o o.-_

_0 0 o

_z> Q.

_D

C_

.,.._

4

¢'N n,"

o,--i

I ._I ._j

,,, 0 l_Z_ O0

m cO

0

TM

--

A circuit is shown and

in its

used

simplest

the previously the

of reconditioning

in Figure

2.

voltage

The

full

wave

ability

circuit total

the

exotic

output

current

at the

current

erated voltage

the

circuit

outputs.

1.5

and to enhance

the for

output

continuing components.

the

the

20 A-h

to

battery No

diodes

the

heat

characteristic

are

gen-

of the

battery

reconditioning

10 W

signals

hot carrier

voltage

a 22 cell,

350 cm 3, excluding

provide

to minimize

cell.

and

circuit

However,

a low

breadboard

output

logic

shown

battery

The

voltage

rectifiers

are

with

each

to assure the

is required. output

converter

associated

The

later

is provided.

s relays

breadboarded

discussed.

with

A/low

protecting

objectives

been

in detail

dc-to-dc

making

resistor' while

circuit

has

in parallel

and

and

previously

of a simple connected

low voltage

A typical

in approximately

batteries

circuit

or circuitry

for

in the

load rate

circuit

to be discussed

decision

sense

desired

components

recommended

for

requirements

This

to approximately

reconditioning

discharge

two test

consists

The

5.

batteries

circuit

is limited

output.

switch

the

rectified

to sense

tested

stated

fo_-rn in Figure

in reconditioning

results

The

to satisfy

low

can be packaged

resistors

and

relays.

CIRCUIT APPLICATION

The

following

breadboard

circuit

reconditioning vary

circuit

in certain

design

and

aspects.

A typical The

tested

has

ditioning

three

battery

cell

reverse

biased.

voltages

conduction. shows

that

hot-carrier

10

are

Standby

the

will

be low enough output

transition

diodes

this

greater in the cell

The this

5, outputs

for

circuit

voltages its

characteristic begins could

be 0.5

V.

system

When

inactive

V and than

and

the

and As

output

1 W for

outputs

of approximately the

the

the

because

at some

occurs

in this

configuration

low voltage

this

by proper

charge

regulator,

low voltage

voltage

could

V/cell

and 2(; ohms.

is less

associated

(1.1 The

are

1.0

drop

of the at a cell

limit

15,

than

application

can be realized

energized.

low voltage

typically power

the

of any

by terminating

to its lower are

to the

be typical

later.

is implemented from

primarily

a specific

that

combinations, the

discharges,

for

advantages

resistors

resistor

would

will be discussed

disconnected load

starts,

voltages

As the battery cell

and

load

unique

circuit

applies

operation

operation

it to discharge

is then

circuit

discharge

but

operation

This

reconditioning

allowing

battery

reconditioning

5.

type,

Some of the

battery

and

of circuit

in Figure

of this

application

on a battery test).

description shown

diodes this

point output

recon-

the are

condition.

one

of the

to begin

in Figure 0.7

V.

reconditioning

6 For

A

(D _

cO

za:_ z ©

_z,_

O_

On "

_w

___

Z az OCh

O0 ZGZ

w

wo

OZ

k-

_.-_

wO

I-'C_

w

0

0

I--

T -J -J w

_j _j 1.1.1

°.-=I

o °.-I

o h0 .,-.I

o ...=I 4_ °,-d

,._ 0 o

, ,,,,,I

\

0

°,,,_ %...I .,-I

\

w

0

_4 q)

0 °,,,_

Z

X

/

>-

w W _,1 w

0

I--

_1 _J

nr z n"w D_ 0

Q Z I_

Z {.2 I

0 _I

0 I-'-

11

1.0

.8 b.J

O > I I.u

< b-.J

o > o.

O

0

0

I

,

i

_

.2

.4

.6

.8

OUTPUT Figure

circuit

begins

to equalize the

until

to 0.5

12

The

load

the and

require

circuitry

signal

discharge

final can

continues

required

discharge, over solar

the

entire

load

to discharge

discharge

is trickle

char_ed

sunrise.

The

the

ntm_ber

capacity.

from is This

at a battery

in parallel

cells

increase

sequence

battery

of orbits,

power

a step

is selected.

at an orbit

a series array

handle

for the

more for

This

value

to completely

the

on line

rate.

resistance

battery

placed

is a tendency

voltages

circuit as

there

cell the

the

characteristic.

oul;put

and logic

the

charge

reserve

so that

The

of the

completes

until

as long and

load

1.0

- AMPERE

circuit

decreasing

decreasing

so that

A-h

cell

sense

rate

V/cell.

completion

to 1 or more on the

the low

thus

outputs

reconditioning

current

at the lower

voltage

Upon and

the

is chosen

of 0.2 low

to share

resistance,

repeated value

Battery

in voltage.

circuit

in load

6.

CURRENT

i

voltage

with

the

the battery. at a 1 A rate charger of which

takes

over

depends

TESTRESULTS

A summary is shown in Figure as follows.

of the results of reconditioning th,e two life 2 and the Table. These and related results

test are

batteries discussed

Battery Capacity The ATM

load

mately

battery

capacities

(Fig.

7 A.

discharged

3) that

The

discharge

rate.

energy

storage

capacity,

voltage

(2). provide

for

is available restores

performance nameplate

to hold

the battery

battery

was

The least

data

last

protecting

cells

slightly

was

first

low grade weaker

at 0.3

in that

The

first

V for

energy and

first

reconditioning subsequent

for

4 days

and then

with

22 800 orbits

resulted

similar

results.

in slightly

V ( 1.1

retains only

its

as described this and

is V/cell)

original

at low rates by

Bauer

limitation rate

and

at which

reversal.

This

upon

completion

of reconditioning

it

apparently the

performance. Original capacity for was 26 to 28 A-h. The time allowed and

to the

the length

rate

of time

and degree

battery

2 was

a 3 day

reconditionings. discharged

for

discharge

capacity

produced discharge

However, 3 days run

restoration

since

the

of recovery.

of each

A method used to determine the degree of discharge to measure the cell discharge current into a diode and 0.5 The data ditioning

battery

from

A 5 day higher

still

plates

the

of 26.4

recognize

on battery

than

discharged

cell

reconditioning

effective

reconditioning

limit

at a voltage

discharge

contribute the

on the

of approxi-

when

is available

procedure

cells

structure,

this

less

and

an average

current

energy battery

energy

growth

with

discharge

degraded

is near its original of the type tested

cells

recovery.

was

plate

measured

protection

of the

circuit

reconditioned

reflect

the

but much

of this

original

battery 20 A-h

voltage

of crystal

extraction while

the

automatic

reconditioning

were

is the available

Apparently

as a result The

tests

in an average

capacity

CBRM

at this and

resulted

recorded

to the

in these

on the

the and

battery

3

second

at approximately in both

batteries.

of the batteries was ohm resistor network.

for the highest cell discharge current in a battery at the end is given in column 6 of the Table. This current is somewhat

of a reconindicative

13

O_

0 ¢xl

¢xl ¢xl

O_

I

I

¢_

_o

_f o hn

0

o

o Z 0

0 I ¢x1 ¢q

¢q

¢xl

Cxi

0 L_ 0 o._

0_

0

c_

o

b-

cO

¢xl

O_

0

_q

oO

O0

O0

LQ

D'-

O0

_D

O_

r-_

Cq

o_

0

Oo

+ c;

14

_"

¢xl

cO

oO

[_-

Cxl

Cxl

Cxl

¢xl

Cxl

of the energy remaining in a battery and implies that, for the cells tested, after 5 days of discharge there is essentially no energy in the cells. However, after 3 to 4 days discharge there is little gain in additional post-reconditioning capacity. Figure 7 showsthe capacity taken from battery 2 on its first reconditioning with the test circuit. The sharp knee at 25 h is the point beyondwhich very little additional energy is extracted from the battery and indicates that 25 to 30 h may provide adequatereconditioning. Until the process is better understood, a test program is recommendedto establish the minimum acceptable discharge time for proper reconditioning. Data to date indicate that a time between 2 and 5 days is optimum.

Battery Voltage Characteristics The

key

age source characteristics ditioning,

and

DOD),

parameters

the

hundred after

points

characteristics

Figure

reconditioning.

than

3 weeks

This

dictates

load

and

and

overheating

that

for

the first

for

the

curve

taken

3 A-h

not been

the

rate

typically

has

at which

the

the

300 or more

approach

of sharing

the

load

same

between

reconditioned

as

a volt-

(15

percent

immediately

up to 15 percent

are

of a newly

a l_attery

the mismatch

the batteries

a method

using

8 shows the discharge immediately after recon-

one which

10 shows There

before

when

Note

except

9 shows

battery

orbits.

later.

match

Figure

reconditioned

consideration

characteristics. Figure 2 prior to reconditioning,

at several

reconditioning. newly

under

is its discharge for battery

after

DOD between

reconditioned

for

characteristics orbits

converge

representing

discharge batteries

a

several more

characteristic. to preclude

over-

battery.

Other Results An unexpected connection

with

two

An erratic approximately compared tions over the with

from

anomalies

that

end a typical

is not known was

occurred

at the

discharged

cell

Figure

cell

with

time. several

voltage

voltage cause

However, capacity

the tests

voltage test,

observed

the

The

the

was

observed

in

the test.

was

11 shows

to the automatic A reconditioning

the batteries

during

in the battery.

present

of 6 months

no improvement.

reconditioning

of discharge

14 000 orbits. with

a period battery

benefit

of the

of the

protection

2 at

erratic

voltage

fluctuations (Note

fourth

in battery

cell fluctua-

were

observed

1 in Fig.

11)

limit

of 1.1

on battery

2,

was

where V/cell then

15

4O

ALL CELLS BEING BY RECONDITIONING O3. re

HELPED CIRCUIT

30

Q

= I,U (:Z: I.U a.

(z3 ,-I ,..I I,M

20

O ¢Z: t,l,.

RECONDITIONING BEGINS HELPING

>I-

CIRCUIT CELLS

¢..)

rj 10

END OF DISCHARGE TO LOAD

(o

_o

io

4'o

DISCHARGE

Figure

7.

Energy

during

16

TIME

extraction first

reconditioning.

._o

do

7'0

- HOURS

from

battery

2

0 Z 0 I-Z (.Jo I_

÷

rf"

? 0

+

0

o ?

rr -_

b_

T

._ ¢.)

uJ

>F-

1,--

0 >

4.1.

U.I

m

_

g

I%(_

,{_

('_

SJ.IOA

0

(%1

- 3D'v'I7OA

A_311VB

17

BEFORE

RECONDITIONING

v_

Z I

°_,_

Z 0

c_

I--o

Z 0

LU C.)

t-

LLI

00

r_

c_ c_

_z

0 _Z _

_w

cD 41

0 U,.

0

r_

Q Z 0 D 0 I-

o

(.D c_

N

0

©

,,....,4

c,D _"

w ct.

>.. j.-

0

<

>. L.U

O0

0

SITOA

" 39VI-IOA

JkEI311V8

17

j l...l

°,,-i

¢o Iii

c.) iii rl

¢D

iii ID

Z

'1-

Z O

C_

I-

ii

z O

O "1I-

iit

01:: ci.

S/70A

18

" 39V.I.7OA

Atd:I.LI_V8

iii

a

°_1

.,i-;i

31 -"

03 I-" --I O > LU

L9 < I.,J

o > LU (..9

A 30

< -j..

BATTERY

2- 9342 ORBITS

E3 U-

O E3 Z LU

BEFORE RECONDITIONING

29

I

I

I

200

400

600

ORBITS AFTER

Figure

10. before

Typical and

end after

RECONDITIONING

of discharge

voltage

reconditioning.

19

w

/

c_

q9

m °,,_

_z

n_

__o >._-

o

_a

I-"

_z <_,,, _mr

'-

O I.I..

4-)

cd

O

_cq

c_ z 0 0 .I-

c_

°._

M N .=I W

..J -J

I

SllOA

2O

/

I

- 39VllOA

II:ID

performed, than 1 year function

and the cell voltage since, the anomaly

normally. The

test

recharge

conditions.

Figure

by three

12.

efficiency tioned,

fraction

After

is controlled

The the

and

recharge

the

cent

approximately

cause

after recharge

collecting

recharge

on the

20 000 orbits,

fraction a battery fraction

again is that

signal

continued

to rise rise.

returned some

electrodes

to increase

battery

to normal. form

as

was

and being

1600

orbits,

shown and

the which

as shown

battery

in

causing was

in the

to 118 per-

reconditioned,

A theory

as to the or

redistributed

gas

during

an

recondifigure.

returned

again

of contamination

under fraction,

to rise

The

to normal

began The

for

to 1.10

recharge

began

temperature again

1.08 the

electrodes,

returned

2 months.

anomaly

1 is normally

signal

fraction

fraction

of this

approximately

recharge

decrease and

in battery

redundant

However, the

stabilized as shown in the figure. In more has not reoccurred and the cell continues to

and

possible

bubbles

is

reconditioning.

1.20

1.18

RECONDITIONED

1.16

I

1.14

1.12

1.08 1" I.,u r_

1.06

1.04

1.02

l'O0_v_

v 2_1

20 THOUSANDS

Figure

12.

Battery

OF

1 recharge

2'2 ORBITS

fraction

anomaly. 21

However, the condition must occur on all three signal electrodes to causethe anomaly. In addition no evidenceof this sort of anomaly has occurred in battery 2. Even so, a reconditioning did correct a situation that could cause battery overheating and subsequentloss. A reconditioning at 2 month intervals would be small cost to save a battery on a mission.

OTHERAPPLICATIONS

The

discussion

of the

circuit

its designed use to protect a battery other potential uses for the circuit The use

circuit

may

it as a detector

for

of discharge across the

to allow

reconditioning when

the

be connected low cell

of the battery entire battery

requirement cell

cell

voltage

voltage.

This

will

individual

cell

voltage

current

sense

The

indicating discharge

has

for

considering

activated

normally

battery

cell discharge and initiate

been

reconditioning.

of discharge protection.

in the

collapses.

far

and

mismatch

senses

and gives an output signal would be used to terminate

5 thus

to the battery

before termination and provide better

for

circuit

in Figure

during discharge are now considered.

Some

continually

to

greater

depth

allow

than a voltage sensor This results from the

sense

circuit

by assuming circuit

the

cell

load

the

detects

or failure. other action

while the

collapse

This signal as deemed

necessary. The failure maximum ure

next

step

bypass. load

modes.

beyond

If the current

Typical

tioning or two,

22

to a good circuit

failure

the

circuit

modes

detection

circuit

are

can open

and

indication

is designed

overcome circuit

certain or short

to

is cell

handle battery

circuit

the failof a

nature inside the cell. Early ceils similar to the type with high impedance shorts that exhibited characteristics

cell

could

and thus

or failure

reconditioning

of a cell, cell

low or high impedance used in this test failed similar

discharge

battery

during supply

prevent

charge the

failure

load

but

had no output

for a small

of an entire

under

number

battery

load.

of cells,

as a result

The

recondi-

probably of cell

one

failures.

CONCLUSION

The restoring

reconditioning the

effective

all

battery

cells

the

circuit

was

system Use

and

while

or assist

the

to be even

sense weak

space

for

future

large

are

both

multiplied

120 series

are

cells

will

systems.

type

The

a circuit

which

were

considered

Earth

orbit

space

are

power

protection

in the

matching

bus

a useful

applications,

have

well. of using

failure with

life

of approximately

a

cell

is considered

of approximately The

compared

to

It is anticipated

scheme

higher

reliability.

discussed Ni-Cd

2 years to last

Significant advantages and cost the techniques discussed herein.

has applied for a patent on this device.

cell

to handle

program.

demonstrated

considered

and reconditioning.

and

been

and

a battery

reconditioning/protection life

is expected

However,

capacity

Skylab

charge

being

designed

test

of power

redesign.

This

in series.

circuit

for

space

terminate

systems

of cell

manufactured

used

useful

to have

either

requirements.

and

flexibility

requirements

and

placed

to build this

The

or component

a 110 V or higher

10 percent

the

a longer

and are still performing anticipated as a result MSFC

like

selection

using

to have

design

in

discharging

typical

matching

collapse

problem

cells

at MSFC

to only

battery

be expected

cell

electrical

to supply

underway

2 percent

no system

protection

designed

using

reversal.

it to an existing

voltage on the

to be effective

against

with

in high voltage

be matched

approximately any

depending

as additional

a battery

Plans

that

discharge

shown

by completely

can minimize

reconditioning/failure

failures, feasible.

cells

cell

useful

cells

results

to this cell

more

combination

the

been

battery

by connecting

excellent

similar

has

of a Ni-Cd

protecting

achieving

it can

discussed

capacity

demonstrated

of a circuit

because

circuit

for

can

batteries, in low

4-1/2

reductions

years are

Application for a license

to use this invention, if a patent is granted, should be directed to the patent counsel at MSFC.

George

C. Marshall Space National Aeronautics Marshall

Flight and

Space

Center Space Administration

Flight

Center,

Alabama

35812,

April

1977

23

REFERENCES

.

Immamura,

Donovan,

Protectors

for

MCR 76-263, .

Bauer, NASA

24

Paul: Office

Sealed

Lear,

and

Silver-Zinc

September Batteries of Technology

Murray: Cells.

Development Report

No.

of Single NASA

Cell

CR-135054,

1976. for

Space

Power

Utilization,

Systems,

p.

98.

Prepared

for

1968.

NASA-Langley,

!977