SAFETY DATA SHEET Based on Directive 2001/58/EC of the Commission of the European Communities
RUST GRIP 1.
Identification of the substance/preparation and of the company/undertaking
1.1
Identification of the substance or preparation: Product name: RUST GRIP Synonyms: none CAS No. EC index No. EINECS No. RTECS No.
: : : :
N.A. N.A. N.A. N.A.
NFPA code Molecular weight Formula
1.2
Use of the substance or the preparation: Coating Professional use
1.3
Company/undertaking identification: Superior Coatings & Concrete Trading Singel 12A NL-7411 HV Deventer Tel. : +31 570 67 29 71 Fax : +31 570 67 03 43 Email:
[email protected]
1.4
Telephone number for emergency: See 1.3
2.
Composition/information on ingredients
: N.D. : N.A. : N.A.
Hazardous ingredients
CAS No. EINECS/ELINCS No.
Conc. in %
Hazard symbol
Risks (R-phrases)
low boiling point naphtha (conc. benzene < 0.1%)
64741-41-9
29.86
F+;Xn;N
12-38-51/53-65-67 (Labelling in compliance with CONCAWE) (1)
straight run kerosine (conc. benzene < 0.1%)
64742-88-7
8.12
Xn;N
10-38-51/53-65-66 (Labelling in compliance with CONCAWE) (1)
16.1
Xn
20-36/37/38-42/43 (1)
6.9
Xn
20-36/37/38-42/4351/53 (1)
diphenylmethane-4,4'diisocyanate
265-041-0
265-191-7 101-68-8 202-966-0
methylenediphenyl diisocyanate
26447-40-5 247-714-0
4,4'-methylenediphenyl diisocyanate, oligomers
25686-28-6
23.01
500-040-3 (1) For R-phrases in full: see heading 16
3.
Hazards identification -
Flammable Irritating to eyes, respiratory system and skin May cause sensitisation by inhalation and skin contact Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment - Vapours may cause drowsiness and dizziness
Printing date Compiled by
: :
04-2007 Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG) Technische Schoolstraat 43 A, B-2440 Geel +32 14 58 45 47 http://www.big.be E-mail:
[email protected]
MSDS established Reference number Reason for revision
: : :
04-04-2007 BIG\44710GB
Revised on Revision number
: :
000
1/1
RUST GRIP 4.
First aid measures
4.1
Eye contact: - Rinse immediately with plenty of water - Do not apply neutralizing agents - Take victim to an ophtalmologist if irritation persists
4.2
Skin contact: - Wash immediately with lots of water - Soap may be used - Take victim to a doctor if irritation persists
4.3
After inhalation: - Remove the victim into fresh air - Respiratory problems: consult a doctor/medical service
4.4
After ingestion: - Rinse mouth with water - Immediately give lots of water to drink - Do not induce vomiting - Consult a doctor/medical service if you feel unwell
5.
Fire-fighting measures
5.1
Suitable extinguishing media: - Polyvalent foam - BC powder - Carbon dioxide
5.2
Unsuitable extinguishing media: - No data available
5.3
Special exposure hazards: - May build up electrostatic charges: risk of ignition - Gas/vapour flammable with air within explosion limits - On burning: release of toxic and corrosive gases/vapours nitrous vapours, carbon monoxide - carbon dioxide
5.4
Instructions: - Cool tanks/drums with water spray/remove them into safety - Dilute toxic gases with water spray - Take account of environmentally hazardous firefighting water - Use firefighting water moderately and contain it
5.5
Special protective equipment for firefighters: - Heat/fire exposure: compressed air/oxygen apparatus - Protective clothing for exposure to chemicals
6.
Accidental release measures
6.1
Personal protection/precautions: See heading 8.2/13
6.2
Environmental precautions: - Prevent soil and water pollution - Prevent spreading in sewers - Contain released substance, pump into suitable containers - Plug the leak, cut off the supply - Dam up the liquid spill - Try to reduce evaporation
6.3
Methods for cleaning up: - Take up liquid spill into absorbent material - Scoop absorbed substance into closing containers - Carefully collect the spill/leftovers - Damaged/cooled tanks must be emptied - Do not use compressed air for pumping over spills - Take collected spill to manufacturer/competent authority - Wash clothing and equipment after handling
Printing date
:
04-2007
2/2
RUST GRIP 7.
Handling and storage
7.1
Handling: - Observe very strict hygiene - avoid contact - Use spark-/explosionproof appliances and lighting system - Take precautions against electrostatic charges - Handle uncleaned empty containers as full ones - Do not discharge the waste into the drain
7.2
Storage: - Keep container tightly closed - Store in a dry area - Ventilation at floorlevel - Protect against frost - Keep away from: heat sources, ignition sources, bases, peroxides, water/moisture Storage temperature Quantity limits Storage life Materials for packaging - suitable : metal - to avoid
: 0/50 : N.D. : N.D. :
°C kg days
: no data available
7.3
Specific uses: - See information supplied by the manufacturer
8.
Exposure controls/Personal protection
8.1
Exposure limit values: diphenylmethane-4,4'-diisocyanate TLV-TWA TLV-STEL
: :
mg/m3 mg/m3
0.005 -
ppm ppm
WEL-LTEL WEL-STEL
: 0.02(-NCO) : 0.07(-NCO)
mg/m3 mg/m3
-
ppm ppm
MAK
: 0.05 E
mg/m3
MAC-TGG 8 h MAC-TGG 15 min.
: 0.05 : 0.21
mg/m3 3
VME-8 h VLE-15 min.
: 0.1 : 0.2(5 min)
mg/m3 mg/m3
0.01 0.02(5 min)
ppm ppm
GWBB-8 h GWK-15 min. Momentary value
: 0.052 : :
mg/m3 mg/m3 mg/m3
0.005 -
ppm ppm ppm
EC EC-STEL
: :
mg/m3 mg/m3
ppm
mg/m
ppm ppm
Sampling methods: 8.2
Methylene Bisphenyl Isocyanate (MDI) 4,4-Methylene Bisphenyl lsocyanate (MDI) (Isocyanates) Petroleum Distillate (Naphthas) Petroleum Distillates (Naphtha) Aluminum, Pyro Powders
OSHA NIOSH NIOSH OSHA OSHA
47 5521 1550 48 CSI
Exposure controls:
8.2.1
Occupational exposure controls: - Measure the concentration in the air regularly - Work under local exhaust/ventilation
8.2.1.1 Respiratory protection: - Wear gas mask with filter type A if conc. in air > exposure limit Printing date
:
04-2007
3/3
RUST GRIP 8.2.1.2 Hand protection: - Gloves Suitable materials: - Breakthrough time:
Nitrile rubber PVA N.D.
8.2.1.3 Eye protection: - Face shield 8.2.1.4 Skin protection: - Protective clothing Suitable materials: 8.2.2
Environmental exposure controls: see heading 13
9.
Physical and chemical properties
9.1
General information: Appearance (at 20°C) Odour Colour
9.2
: Liquid : Aromatic : Grey
Important health, safety and environmental information: pH value Boiling point/boiling range Flashpoint Explosion limits Vapour pressure (at 20°C) Vapour pressure (at 50°C) Relative density (at 20°C) Water solubility Soluble in Relative vapour density Viscosity (25°C) Partition coefficient n-octanol/water Evaporation rate ratio to butyl acetate ratio to ether
9.3
Nitrile rubber PVA
: : : : : : : : : : : :
N.D. > 150 44 1.4 / 10 N.D. 1.1 Insoluble N.D. N.D. 0.32 N.D.
°C °C vol% hPa hPa
Pa.s
: N.D. : N.D.
Other information: Melting point/melting range Auto-ignition point Saturation concentration
: N.D. : 214 : N.D.
°C °C g/m3
10. Stability and reactivity 10.1 Conditions to avoid: - Unstable on exposure to moisture 10.2 Materials to avoid: - Keep away from: heat sources, ignition sources, bases, peroxides, water/moisture 10.3 Hazardous decomposition products: - Reacts on exposure to water (moisture) release of carbon dioxide - On burning: release of toxic and corrosive gases/vapours nitrous vapours, carbon monoxide - carbon dioxide
Printing date
:
04-2007
4/4
RUST GRIP 11. Toxicological information 11.1 Acute toxicity: diphenylmethane-4,4'-diisocyanate LD50 LD50 LD50 LC50 LC50
oral rat dermal rat dermal rabbit inhalation rat inhalation rat
: : : : :
9200 N.D. > 10000 N.D. N.D.
mg/kg mg/kg mg/kg mg/l/4 h ppm/4 h
11.2 Chronic toxicity: diphenylmethane-4,4'-diisocyanate EC carc. cat. EC muta. cat. EC repr. cat.
: not listed : not listed : not listed
Carcinogenicity Carcinogenicity Carcinogenicity Carcinogenicity
(TLV) (MAC) (VME) (GWBB)
: : : :
not not not not
listed listed listed listed
Carcinogenicity (MAK) Mutagenicity (MAK) Teratogenicity (MAK)
: 3B : not listed : -
IARC classification
: 3
11.3 Routes of exposure:
ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms: - AFTER INHALATION - Irritation of the respiratory tract - Irritation of the nasal mucous membranes -
EXPOSURE TO HIGH CONCENTRATIONS: Headache Dizziness Nausea
- AFTER SKIN CONTACT - Tingling/irritation of the skin - AFTER EYE CONTACT - Irritation of the eye tissue 11.5 Chronic effects: -
May May Not Not Not
cause sensitization by skin contact cause sensitization by inhalation listed in carcinogenicity class (IARC,EC,TLV,MAK) listed in mutagenicity class (EC,MAK) classified as toxic to reproduction (EC)
- ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: - Respiratory difficulties - Skin rash/inflammation
Printing date
:
04-2007
5/5
RUST GRIP 12. Ecological information 12.1 Ecotoxicity: diphenylmethane-4,4'-diisocyanate: - LC50 (24 h) : >=500 mg/l (BRACHYDANIO RERIO) - EC50 ( h) : >100 mg/l (DAPHNIA MAGNA) 12.2 Mobility: - Volatile organic compounds (VOC): 45% - Insoluble in water For other physicochemical properties see heading 9 12.3 Persistence and degradability: - biodegradation BOD5
:
N.D.
- water
:
- N.D.
- soil
: T ½:
N.D.
% ThOD
days
12.4 Bioaccumulative potential: - log Pow : N.D. - BCF : N.D. 12.5 Other adverse effects: - WGK
: 2
(Classification based on the components in compliance with Verwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 17 May 1999) - Effect on the ozone layer : Not dangerous for the ozone layer (1999/45/EC) - Greenhouse effect : no data available - Effect on waste water purification : no data available
13. Disposal considerations 13.1 Provisions relating to waste: - Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 08 01 11* (waste paint and varnish containing organic solvents or other dangerous substances) - Hazardous waste (91/689/EEC) 13.2 Disposal methods: - Recycle/reuse - Remove to an authorized plant for the destruction, neutralization and elimination of hazardous waste 13.3 Packaging/Container: - Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or contaminated by dangerous substances)
Printing date
:
04-2007
6/6
RUST GRIP 14.
Transport information
30 1263
14.1 Classification of the substance in compliance with UN Recommendations UN number : 1263 CLASS : 3 SUB RISKS : PACKING : III PROPER SHIPPING NAME : UN 1263, Paint, Special provision 640E 14.2 ADR (transport by road) CLASS PACKING CLASSIFICATION CODE DANGER LABEL TANKS DANGER LABEL PACKAGES
: : : : :
3 III F1 3 3
14.3 RID (transport by rail) CLASS PACKING CLASSIFICATION CODE DANGER LABEL TANKS DANGER LABEL PACKAGES
: : : : :
3 III F1 3 3
14.4 ADNR (transport by inland waterways) CLASS PACKING CLASSIFICATION CODE DANGER LABEL TANKS DANGER LABEL PACKAGES
: : : : :
3 III F1 3 3
14.5 IMDG (maritime transport) CLASS SUB RISKS PACKING MFAG EMS MARINE POLLUTANT
: : : : : :
3 III F-E, S-E -
14.6 ICAO (air transport) CLASS SUB RISKS PACKING PACKING INSTRUCTIONS PASSENGER AIRCRAFT PACKING INSTRUCTIONS CARGO AIRCRAFT
: : : : :
3 III 309/Y309 310
14.7 Special precautions in connection with transport
: none
Printing date
:
04-2007
7/7
RUST GRIP 15.
Regulatory information
15.1 EU legislation: Classification according to directives 67/548/EEC and 1999/45/EC
Harmful
Dangerous for the environment
contains:
low boiling point naphtha; methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate
R10 R36/37/38 R42/43 R51/53
: : : :
R67
:
S(02) S23 S24 S33 S37 S45
: : : : : :
S61
:
S(63)
:
Flammable Irritating to eyes, respiratory system and skin May cause sensitisation by inhalation and skin contact Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Vapours may cause drowsiness and dizziness (Keep out of reach of children) Do not breathe vapour Avoid contact with skin Take precautionary measures against static discharges Wear suitable gloves In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Avoid release to the environment. Refer to special instructions/safety data sheets. (In case of accident by inhalation: remove casualty to fresh air and keep at rest)
15.2 National provisions: The Netherlands: Waterbezwaarlijkheid: 6
16.
Other information
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. N.A. N.D. (*)
= = =
NOT APPLICABLE NOT DETERMINED INTERNAL CLASSIFICATION (NFPA)
Exposure limits: TLV : Threshold Limit Value - ACGIH USA WEL : Workplace Exposure Limits - United Kingdom MAK : Maximale Arbeitsplatzkonzentrationen - Germany MAC : Maximale aanvaarde concentratie - The Netherlands VME : Valeurs limites de Moyenne d’Exposition - France VLE : Valeurs limites d’Exposition à court terme - France GWBB : Grenswaarde beroepsmatige blootstelling - Belgium GWK : Grenswaarde kortstondige blootstelling - Belgium EC : Indicative occupational exposure limit values - directive 2000/39/EC
Printing date
:
04-2007
8/8
RUST GRIP I R C a: d: du: fa: fi: fu: p:
: : :
Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil Respirable fraction = A: Alveolengängiger Aerosolanteil/Alveolar dust Ceiling limit
aerosol damp dust Faser fibre fume poussière
(vapour) (fibre)
(dust)
r: st: ve: va: om: on: part:
rook/Rauch stof/Staub vezel vapour oil mist olienevel/Ölnebel particles
(fume) (dust) (fibre)
(oil mist)
Chronic toxicity: K : List of the carcinogenic substances and processes - The Netherlands Full text of any R-phrases referred to under heading 2: R10 R12 R20 R36/37/38 R38 R42/43 R51/53
: : : : : : :
R63 R65 R66
: : :
Printing date
Flammable Extremely flammable Harmful by inhalation Irritating to eyes, respiratory system and skin Irritating to skin May cause sensitisation by inhalation and skin contact Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Possible risk of harm to the unborn child Harmful: may cause lung damage if swallowed Repeated exposure may cause skin dryness or cracking
:
04-2007
9/9
