Sample Copy. Not for Distribution. - Educreation Publishing

Sample Copy. Not for Distribution.

RS ORGANIC CHEMISTRY @ YOUR FINGERTIPS

i


Publishing-in-support-of,

EDUCREATION PUBLISHING RZ 94, Sector - 6, Dwarka, New Delhi - 110075 Shubham Vihar, Mangla, Bilaspur, Chhattisgarh - 495001

Website: www.educreation.in ________________________________________________________________

© Copyright, Authors All rights reserved. No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form by any means, electronic, mechanical, magnetic, optical, chemical, manual, photocopying, recording or otherwise, without the prior written consent of its writer.

ISBN: 978-1-5457-0848-4 Price: Rs.486.00

The opinions/ contents expressed in this book are solely of the authors and do not represent the opinions/ standings/ thoughts of Educreation or the Editors .The book is released by using the services of self-publishing house.

Printed in India

ii


RS ORGANIC CHEMISTRY

@YOUR FINGERTIPS A Complete Quide And Solution For MEDICAL AND ENGINEERING ENTRANCE EXAM

Written By-

Rumana Fatima Written AND Edited By-

Kamran Ahmad AND A TEAM OF IDEOVATE ONLINE STUDY GROUP (IOSG)

EDUCREATION PUBLISHING (Since 2011)

www.educreation.in

iii




IOSG GROUP1. 2. 3. 4. 5. 6. 7. 8.

KAMRAN AHMAD (Co-Founder) ASHISH ARMAN TARUNAY SINHA Dr. SHOAIB UZMA ISLAM Dr. SIMRAN KHAN Er. ANJALI CHATURVEDI RUMANA FATIMA (Co-Founder)

 1. 2. 3.

SPECIAL THANKS TODR. Zeenat Kaifi (Scholar Of JNU Delhi) Er. Fatima Ahmad (Graduated From IIT Delhi) Sadaf Ahmad (MBBS)



ADVANCE THANKS TO-

1. ROMAN SAINI (IAS, AIIMS Graduated) 2. Dr. Anand Rai

(Whistleblower-Vyapam Scam ; Opthalmologist)

iv


YOU CAN FOLLOW US FOR GIVING FEEDBACK AND SUGGESTION Twitter- Rumana Fatima @su8260 AND Kamran Ahmad @i_kamranahmad Instagram –i.m.ru AND i.m.kamran_ahmad FB PAGE– IDEOVATE OLINE STUDY GROUP GMAIL – [email protected] For BULK order i.e more than 50 book And Distributor‘s enquiry. Mail on above given gmail.

v


Dedicated To Our Parents And Also To Our Grandparents For Thier Love Respect And Prayer A Special Thanx To Our Brother.

vi


Acknowledgment ―Learning gives creativity,creativity leads to thinking,thinking provide knowledge,knowledge makes you great‖.This is a famous quote by our beloved and most respected President,The 11 th president of our country-DR APJ ABDUL KALAM who have inspired millions of youth and students.So,We would like to thanks him from internal core of heart. We also like to thanks Zeenat (aapi)- A PhD Scholar from JNU and ESPECIAL thanks to Farhan Ahmad. We would also like to thanks Aman Verma , Anam Fatima and Ashish Arman for their help AND special thanks to EDUCREATION. At last we would like to thanks our PUBLISHER Ms Shradha and her team mate for immense effort for giving final shape of our book.We also like to thank typewriter who typed for us AND ESPECIAL to thanks to all my friends and juniors (Afreen Pervin,Abhilasha,Uzma Islam,Ashish Arman,Tarunay Lavange and Saransh Kumar) who made easy path for us to publish edit and distribute the book.

vii


Preface The idea of writing book came when we were individually preparing for the entrance exam and not satisfied with the way Teacher or INSTITUTION used to teach. After some time when we meet different juniors,friends and classmate they all had similar story regarding this issue.So,we than decided to share our notes which we had made from different sources,modules of different institution and from different books in a SINGLE BOOK in form of e book and paperback.This is how we came up with the book-―RS ORGANIC CHEMISTRY @ YOUR FINGERTIPS‖- a complete guide of organic chemistry for various entrance exam. If you RELY on this book,we can assure you Organic Chem will as easy as possible along with ‗CLEAR CRYSTAL COCNCEPT‘.At last i would like quote few words of Bahadur Shah Zaffar so that all aspirant may get motivated when they open this book. ― In hasratoun ko keh do khi aur ja bashai, Itni jageh nhi Dil-e-dag dar m, Mang k layai thai char din , Do arzu m kat gye do intezar m”

viii


Sailent Features         



Concept Covered with for every single topic. Cocise Theory Collection of concept based solved question asked in different entrance. Cocncept is dealt in every Ques which seems to be necessary. Key Point,Note and Fact is mentioned under seprate box. Clear Crysral Concept is dealt with ques which is termed as „CCC‟. And Concept Building Question (CBQ) is dealt Tricks for solving question. Tips and Review for imp topic. 80%-90% ques has came from the CONCEPT of this book in various exam such as NEET, JEE MAINS, AIIMS, JIPMER .AND55%-60% ques has came in IIT (JEE ADVANCE). From RESONANCE TOPIC to REST TOPIC of this book which is V.Imp is dealt with CONCEPT IN EVERY SINGLE OPTION and TRICK for solving ques i.e which concept is to be used in every option and what is trick which can save time in exam.

We have only written this book with a view that average and student who can‘t afford institute can get maximum benefit.As coaching institute not just EFFECTIVE for entrance now a days . AND also to prevent students from getting misguided from large number of refrence available in market.

ix


How To Start Preperation 



Before Starting preparation you (students) just need to about the pattern of exam ,syllabus and everything useful thing which will help you in preparation of smooth flow for exam. As Syllabus is too big so it needs SMART PREPERATION.SMART PREPERATION means By studying least possible book you can afford maximum marks possible in entrance.

BOOKS TO BE AVOIDED MEDICAL ASPIRANT PHYSICS – HC Verma, DC Pandey, Walker, SL Arora, ERODOF and all this kind of book. CHEMISTRY –Modern ABC ,Pradeep, Dinesh ,Organic Chemistry by Robert Thornton,Solomons and Fryhle AND by Peter Skyes.  Instead of reading all these book of organic chemistry ,RELY on my organic chemistry book – Organic Chemistry with Concept and Trick.this will help you for better score. BIOLOGY- All book EXCEPT NCERT.Presonally, We have went through all these book during preparation and found worthless and just waste of time for ENTRANCE exam as you have to give ENTRANCE EXAM –NEET and you need not have write PhD thesis.

BOOKS AND REFERENCE TO BE USED PHYSICS – NCERT must + Class notes + package is sufficient  If you (students) want us to share our notes of PHYSICS than give us feedback on gmail or website. CHEMISTRY – NCERT must+ Class notes + package AND for ORGANIC CHEM – our book ―RS ORGANIC CHEMISTRY @ YOUR FINGERTIPS‖ is best as it is collection of different book.

x


BIOLOGY – NCERT must (only) + if you want reference than you can prefer RAHUL CHAWLA‘s book.  Imp Fact of exam –  NEETBIO- 90% ques comes from NCERT. CHEM- 80% ques from NCERT + 80%-90% ORGANIC CHEM Ques will come from CONCEPT of this book. PHY- no fix % from any book BUT more or less ques is Easy and concept based i.e 80% ques there is no mixing Of 2 concept in single ques.  AIIMSBIO- 70% ques comes from NCERT CHEM- 60%-65% ques comes from NCERT and 70-75% ques of ORGANIC CHEM will come from the CONCEPT of this book. PHY- little Tougher compared to NEET as there is mixing of concept in one single ques which is asked.  For Assertion and Reason you must have to read NCERT book as it is directly or indirectly from NCERT only-there is no substitute for this.  Solve all 3 sub NCERT book‘ss ques.(imp for clear crystal concept)  Practise as much as possible.  Concept should be CLEAR CRYSTAL – basic need for qualifying exam.

xi


Contents S. No. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12.

Title Important Table Important Reagent and Name Reaction Nomenclature Isomerism Tautomerism Geometrical Isomerism Optical Isomerism Resonance Effect of Chemistry (I/ M effect etc) Reaction Mechanism Naming Reaction Review for student

NOTE-

xii


Page 1 13 28 44 54 60 69 105 136 183 285 306

Important Tables

1

PRIORITY OF SOME FUNCTIONAL GROUP

Functional Grp -COOH

Trick

Prefix Name

Car

Carboxy

-SO3H

Sulpho

Sulph

-CO O CO

Water loss

Acid Anhydride

-COOR -COX -CONH2 -CN -NC -CHO -C O -OH -SH -NH2 -OR C C C C N2 NO2 NO X

east Alkoxy carbonyl oil Helo carbonyl Mobil oil Carbamoyl Cy Cyano I Isocyano Al Formyl Ke Keto /oxo ol hydroxy Thio mercapto aim Amino ? Alkoxy

Suffix Name oic Acid Sulphonic Acid oic anyhdrdide Oate oyl halide Amide Nitrile Isonitrile Al One Ol Thiol Amine Alkoxy

Er

Epoxy

Epoxy

C=C CC Azi night so helo

ene yne Azo Nitro Nitroso Helo

Ene Yne Azo Nitro Nitroso Chloro

1|R S O R G A N I C C H E M I S T R Y @ Y O U R F I N G E R T I P S


Trick For Remembering TableOne man is driving Car and found no Sulphur in car due to this Water loss began .He travelled to Eastand tookOil and Mobil oil. Some body asked him in other language What is your aim (CyAlKeOl, thio (tmhara) aim? ). He replied Engineer. Work of engineer is to build home. Therefore He will build first two storey building (C=C) than three storey (C C).After returning home he wanted to have chat with wife but she refused and told Azi Night ,So (sleep). He told Helo listen. Water loss- Acid anhydride

R u ma n a F a t i ma , Ka mr a n A h ma d |2


Important Tables

FEW IMPORTANT TABLE IN SUMMARY FORM STRUCTURAL FORMULA CH3CH3-CH2- or C2H5CH3-CH2-CH2- or C3H7CH3-CH2-CH2-CH2- or C4H9CH3-CH-CH3

IUPAC NAME Methyl Ethyl Propyl Butyl Isopropyl

CH3 

Isobutyl group

CH3-CH-CH2Sec. butyl group Tertiary butyl group Isopentyl group Neopentyl group

Tetiary pentyl group Isohexyl group

3|R S O R G A N I C C H E M I S T R Y @ Y O U R F I N G E R T I P S


Get Complete Book At Educreation Store www.educreation.in



Sample Copy. Not for Distribution. - Educreation Publishing

Recommend Documents