LAPORAN PRAKTIKUM KIMIA DASAR II/ORGANIK PERCOBAAN C-2
's L
ab
Re
po rt
IDENTIFIKASI SENYAWA ALKOHOL DAN ESTER
Nama Nama Partner
FakultaslProdi
Mandela IYIM zZA14l365676fPNl6l32
M an de
: Jason
la
Disusun Oleh: : Ilita
Agustin NIM 2201413656721?N16131
: MIPA/Ifimia
: Seninl20 Aprit 2015/15.00-18.00 WIB
Asisten
: Andini Nila Sari
Ja
so
n
HarilTanggaVJam
LABORATORIT]M KIMIA DASAR
F'AKTILTAS MATEMATIKA DAFI ILMU PENGETAHUAF{ ALAM
T]NIYERSITAS GADJAH MADA
YOGYAKARTA 2015
T- dentl.f i l^4,, Sengora Al [,to ho I 1).l;,rjuan l].roboon Me*pnla.1a r, , ester
s
iJat - si{at
drn
Este"
altohr
seoga.Luq golrngon
l
drn
[) D*0. Teori
Ca\ah se[o\orvrpotr atoo q40.1 Sctanllu "r1 'ra*ob Guou, {rnqr, u* atas ,,IotJ ,tr'.., oin[r*l tpcrebx I Molel,1* I b]rbdd, Ur.i nYeilriri,' quq{s {unqs; sqma aLan rnar^nrlrhi realrs; garJ ;,l,p,Dunqo^ ttorahtet
b,ro' ri^pa^io", do.
doti
mennoho-
zo,, ) Bubecqpl 6e.'{oh
i
bnbecqPo
srfat
grgu
iA\t^rLo\
s
}1s;
sengar.va
adoloh sebnjot h^lr^1,
Re
I
i'^lr','L':+o
,|ot- dr.i
- sr
otoCIn,\n (Chono ,
t
3u3',.s,
po rt
tl*rar3r.l sifat
ab
A\[^rUrt mo*r\,[, quqqs hi dro[,,' (quqr. C'l-{) Uanq lerfiql t. tr tl'o 1.,, denqan ,obu^h ato. \,urbo n be,. h U r ld'"*r sp I
rnrniad.i
sehurdp,
la
[rrher,
M an de
Itl
's L
Ir,t , "'1", \ R-c-ot+ R-i-cru
drf,\or,{,
,
, ()on' tPrs,er.
r
R-c-or+
HHR ln
7o
ra[,runc{0.
pcimer
teruter
5o\oh ,o{,u -n {6hnqa arhlqh s+rnol [Ct-,sCH menlcrst llo",boh,clrot (5^ilh , zoto clor.; te, L' J
).
drbentq I , qatu4 \r {
l:te. Ete. te.d,, i darl d,r* quq{,(s oll, i \ qorl tcrrlr q t ole h tu o\^,,Xen , I,teduq Xqu." "q\1{, Ir,rol io.o c^to a b.bnc{t R_ C R,
so
2).
z O [-t)
n
\
3o
so"-
Ja
I
tstruhtur Ucnqrn )
ste. odrtah dre-lr I ete. L\ahLl dolru \u jrqurq[6,r Edqa, obat biu, (B.odq, aoiz )."
5o\qh
salu
co
ntoh
u
g) Aro.n' I(,o.bol,-, lat'
alo* 11',b:: $-.] gu$us Ito,bon,i [C=o) d,l[at o\eh Ququs h, dtol ti ICH ). S"Zo"rq
Doh* ttmur.n
sebuah ctsorn i,,r'botrsriat,
, 0uquS
{ur.nq5i
n{tt
c,rlatoh
"tn"L*gia bn. rllq
I
t
?
-
5q\*h sabu 6srrfohrul
*oroa
fil;
elonoot
cul,l.ci,v,o[,t*nfT. *be,.Ia he' Totq)
.la\(-
$rng
terdapat
,) Este r
s CR gonl bn1'l''ton d'n:on , 1,'3u,t derr yc(l da rt 0sqnn horbrlrs r)"t. ho..bon,\ Esh. ,ile6[^n
Ertc. r. *,\,lni
tulu
- A- o n'
"
Re
Pe.coborn
,. Alat dan
Bahon
l[ I i] Al,t
Alat -o\at uonq d'quna\ran dCI[r, P?rcnboon inr 61da\oh p,pnl +olpi, t*,rn penguopan I,to*L o,p; , pen;epr.t besi' {abun, real,tri , lah tabnnq rbahrr , qeiat .,.tkrt [0nn L b"to.t' kmba3a (tr) o[',di, pornan'.' tP'r.tus petnanas Gic , dan l,te.tas sar ln3 z). Balro^ Dohor \lonq drqunoln^n adatoh Pe"L.rleu- e{her-, etuno\ ,;.of;;ii ar^uor.,.t , metil *it^oh, i,' I{aqH,l0% ' Hr90. onirt,t I'r/t'in'0-* ., ql[6ho[,, isoarn'1 alkohuir aso,"n
'
.,
lTf-
t
M an de
la
's L
I
nenn'Ll'ri
ab
). Mntran
po rt
(st.ut,tu. u*un erte^) 5a\rh .otu co1+o)q" qdalah .neti\ butonoal $'T bo, sepe.{i oPel IBr-uice , ]0 t', ). R
n
;;[;'ir[,
do-n escrin
'
oluL+ giasrqt [10'/a)'
so
U z) Cs..r lAe.3o
Ja
I"z
r). Pe*brtr*o^
Alhoh'1
sel't'e datar,n cawon bt.o\nunn etec d'''opl'on ,qnn,l"oPo?
I^+,..'{nJu'.ile*ud.a.,pe.lroleuanele.dltba|,tco,fleo1an t'l;oa dra r"'a,ti Pro"t
l^r.oh
api Fu;*;";
;;^;
dq'n
u6^1 isoprcpri qll'1ohol'
sarnq dr\ohulnon ,Jrnguo.nu.n{,i alkohol U 2. L). ohsrdasr altroho \ U z 2 1) o[srdost deoqan }{olru* ftrrongo,.,q{ l2rnL aindan Sak.url, '5,f, lrvrL rne{r\ ,"lhrhol dconnpu"[o., ionqao \n.r+** o, 1,, dalann i,q^ tobnna r e alt t ' L'ol* a rr rjl4q ,, brl.\t^ hn doto, tob^3 .nI[,,, he ei"pol Satu {etes t-laC[-l to%
d,ta*hahhan he dalqr^ {.tbunq ,pg. tomg
5at, teles l-1r Soa l,tMnoq il;i J,+rrfrht * ['o dnto.'+[Oun3 he,dtq. La.ut* {eles i*r-oit^r^ h, dalom l,,eapnprt lahoil sebo"^k sal"' g^nl sq(nq PrJttaut Oi"*+' ' 6.1of,r' na L{on'1 wcrr Pnubqh^ d,\a\r\nn donq^' itlp.op,[ alIoholda T z.z z).Oi,,idao denqan Te*boq^ Clr)olrsr et,l
altrrh, i lolq dt p*q t hon ,r, :l;r$"n ,,1I rn o Lsrdq di panas l,'an f,.,art^"i*lpoi-*ondrd'h' La\Jt f^1*t ]eonb'gi tob^ry reair" fonpa hn ailo-tennbrq' c/'mqs'l'h'n "i.^ Lrlu l^rrat t1""1 L'- b^[' dan [ ,q, oh"cl'^ .'d,roLr\;''ffilr*
"h;';;l*
tnrcn\,,rp.
dr..lupLfI[. z ' r) Pe*ben{'[*'
loro*'oo tprseb't'
Tof,q
t'
dot'3'n [le*'t' on [-lzSoq o's-L osarn aietat glorMl ; io *etps :
'
Fle
so'{ Pt't't
-' *,o'
's L
E'
; 0's t'rL ,sqrn d $q+ glor'"[
isoqmrl q\Lohul
k+ut
Tob*3
ab
irT)*alttoh'l;
Tab,,r1n. tii;l
'Ba* uqP dr ctt/ rn'
Es*er
{obun1 req[,r, dtt'
Tig,
po rt
d,
Re
Tobr^a redLi
] i0
qtLoh't
;
M an de
la
fi:";:"!]dtilf .:iui;-J,,.' ul,l',ffii1'*'' l' il:H''i'* .J;i; r HHr oli-u},t Y,'*1,:^* boung, dtcturn.
&,n
don Pn*boho, o n Ha, '1 N l). Hq,,'l U' 1 . r). fu*bo[o.*, olLohoI
n
N)
[{o.ohiori.litn \lg*ta
so
Boh^n
api besai, \rotna qpr huntn1, bogion $ongrh c{pi
Ja
Pet.o\nu* Ete.
Et'i
qpr hir,
Alhohrl
I.oprop'l
Altroh"l
opr .r
becur-ocna
liun;.5,
ctp
,
b,.,
leb ,
h
bn,
o,
I\-
dact fL rg. .1 "
l)
Olurdasr attrohol qi.0irs,dar' doogrn halrq. ppp6v,e'^q*nrt Cbn..*rnq t,.nft @a+)
Aet,l
+NagH +
Altrohrl
hMnOq , 6e\,tlat
+HzSgq *ltflnflq :
.
I
I,{n
0
r.
A,, + hlltn 0,
b inq
Jecnth rnerah ba*o,
; Un(d i,ii Je r.nt ir : ttoau Pol,olt
Jsoprrpr
Alttoh o
+NaoH r hltln 0q : collat +Hzso'jr +hllnO, ' cahlqt
+itlt{ngr
Ar. +[.lln0 q
t
,Jer plla hecrzh
rco[,t[at je,n,h
' un{u
.icrnrh
bJ.Oi^,,doti dengan Te*bogo[ll)olrtao metrl alhohol"' bqu rneoXungat
i
l). Pe*bunt'i[ron Ette..
Tobung
b*u
ho\un gele.nbunq
Tabung
bau
pnrfu.,,r
labu^g
bou
ba\senn
po rt
N
N z)Pe*hh*on ., , , '' besor diopi alt'oh' 1' pemba[oton pe..coboon $0n3 , P'l'ng P-; "lni t$;;fr.g,\-'rint efec' Pado, pi"'o,b;rn ' ngo)a harrllorn rytrole,,tm opr Llnnq drhaLrl\,r oo PE drn isoprop,\. altroho \ l&, h dorntn, n ber*or-
Re
,
dori'non etri allohol rnerntlrIi warno,,rgol,, apt, \^,i;i.lq lar^rf,rn 'oleh "-;il;^rul^ton drha"srlhon perbolnrrruhu opi te.ponr. b;r'.'" Uof ',!ahwa ';, pun *nnunfulrh" efi[ al,trohol pa'ling wn' ,n * f altrohol -*ott,,n' ourna te.bahaa. Semohrn sernputna 0efi bo[,ta la n rnatra ,o h io {'in4q i d,ha!,llr^ i,rodo. C" ld^3 drhasr\han drh *al,r,h rendoh l,rodar. C0 go^g u Poio pu.*boon o\rsrdasr ull,trhr\ deogon tf hO,. d,\g,l^uL,on
;;;;'bn.uori,stpuda Jur- teni: mrle[r]
M an de
po.iahuan
la
's L
ab
il
il.'i--if,rlrlJ C;;ril,;[ij 'd*n
rnetrlu al[oh,l a'lkoh,
dr\a[u[r^ pgqrbqhon hnoL' puda ,eh\ ottrohu'l '
i.[*^
\
) 'q*']r
rsoalliohr,..l Cr'alliohol PodX tabunS
dengon Na 0H don WMnlqo
puda
so
Realir'
n
HgC-cH + l'{Mno" -$-) '*3-'* metono I Osanrr
Ja
HrC
I EoP
forrnat
coP'\ altioh,
I
CHs
- C}|- Ot'i +
o*
I
fiMn0q
',
o
Hc
c-B-.u.
2-PfoPonon
lsoPrP'\ a\l^oho\
Pq\arn h"\ rnrr NooH berPecon snbogai l,tatohs " Padq ouno[o^ He5oq sebsqo , h o tq lis o deo\,r, podo rne{'\ ,fioh'\ ' tt H+ H - C- Ol-l HtC-otl ftMno''
tabung kedua' il'
.
+
ReoL,r
poda
,toP#f
,\
altaohol
'
lr
*
,o
[t
HIC-CH-ot+ t e(Mnoq -L) Bd" tqbunq l,tetrqa d lla[,to[r* penannbah^ le. i rd, i,o..rn* I,tohol. Tidal,tu odo iu*trr,
Hr C- c -
CHs W
un
0
o eolot pad^ al'
lal, odmla trutolr,
.
Ho\ rni bt.o te.\rhc,t
darr
perubohan w0rnq,
,
dr tunlu t4van. Dadq
t:!i':Y' !4r' '' ull lrruql 'vtwr 1,+[ll;::i,.,[:" tnl,utlo 1,,{0nq a,t,,tr.ur, , I I 'i ffiT ]:iC .J,'J{,;f" rnenladl Qol'tlat Ungu ki:ii J
r(n
[\4
-.frrI
Dpruhahan Luafna.
ffi,Jil'^ otl,Arr, Jv\r \ u'r
dati Perubrhon Warna "runuo*o
otf^onri
dari 'srsa rcaL'' ol,,'r-
!1nc:-
tu;J;;;il;
P;;6;ri
d,asi . Hq\iur^
L4anq
adalohu
i
plme.v rnenjad
[;ur" ffi; pr;i;n o\rsrda h.1udr'reohit t
o1,s
idato.
.esar"rn
\,r".b,0
sshin*la [rsa
,
"t
^ melanc'l dongon le*bay6t)
do"
oL''
!rit Ltllat
r^-
r
6t
o
Hsc-ot-l 9"o' ^H-|,-,n fot'noidehrc'\ cr^rolano\ u;:;:;'l!?'-o':'i hfi:,
po rt
t
Fi.n"q'it^T:,x-u:,X.[1'j' x*, [: ro ro ( IIlJii,* ilt; ilt,"i iu'. s''th' adal'h' pervrbentul'on €ster' D'Saoqa t^
Percoboon so\'n1utn'i' "Jii11,ri^ri.' .r1?.,i,t,'o''' pe c.obao'J",'.,
ab
la*
)
Re
fu['r
de'
g'i-
's L
^*]|;I,'U^^ hufiocnt/_mencqrnp'',I'onoft^i'tdlnatotlffi'boLs'lalde' Hr.i'u' pu*ono a n " Padq tab'n" I drl a\tult,.n
s o'"hf Realisrog* adqlah dto.r{rLa,, oo;'*l^rtl"'u'l'';;i Hdo.r ? + H'o :* i*o"ii;.onLrj3 Hsc-cF+ + C\-reeooH s
:
M an de
la
nqurn lnatalr
percobaoo r a\,tgh,.menXhost\lrm', botr t)qnq lnhot . Pod," 'fo.snbcrt '\";; 6,[iT, \i^r" bau baro n qnln..n{br"q Bqu lahas fibi.,r Lo'lu pada percobaan dihrrrl Lr* an[ t+if atebot IBr,r,tn )zor" )' Senuaw a
sste '
L
labunX
dr\aLuhon
e5terr{rirosi
n
CHt t
Urnl rvrenght''ll't* '::J;';, l,H-*"U cHs o HrSol ^ " U
so
HgC- Cu-Cltt.-cLle-01+*CH3@H-_-)HrC-c-o-Ci,le-CHz-CH ltro CtlS +
Ja
hu p.{urn r{g.'q dihost\ ilon hchont't'r Bau
po.{r*
dqr
lo..,,'tbut rn*iP flongan bo^
Lo\u Duda percoboo. tobuS lrthqt nnenqhasl\\,ran nnett\ Ea\tt'\at
d"u Metrl sol,r r\ot
tA
U0
+
CHr
-
rnb\e[r"l
tsoqm
i\
qse{a*.
pir ahu
P\san3 [B.u,.n"zotl)' drio\,rrtton es{eri{ rt'rall qag
o*zoc,Hr
c\roH ol'l
1
#)
l-laSctq
rtout
+
HrO
* rui'soirs,la
adaiah bqh^ da r ( bal se rn a*au oba t r
d a n{rl,t
)a^n
qo sal) mrl^q
bo, te,reBrt (Srnrt
odalah reo\,rt reversib]e dan lqtrbqt Esler gang l,tara,a itq, drlq,Lu\t,n yten,u: ;;h;,;\il ti;;l ir.trt, bongrt, olehFtU: a[r'n fp,.tqha1 Yd? " onqan \firrtrn \,; hett'{"'ot':? drdete; si l-otu paleLru snh,ntrq, teiinUui , T,d, [.1i,, mernr percepai rcabs'' untv\, bu,ir']ur^ di\qLuLan mona\,n u,rq . ^,.t { briq leil*h hngah rv'enXharrtiran esfer esterr\,l,rss;
Rnol,,,\ es+erilr1q.i
h
;.';;i
; t*,;
). r.I,{nt,*pu \, n r). AtUofot r,'emr\ihr srlat ryudol. . tc'.bol,ar dm bl[a forolrurda" si di,ton .nnqhoslil,ran aldehl d , \'1eto n atau asCI M l,trrbol,t' sr\of , A\l,tohoj Pu^ mudah menq'raP' r) Ester rnemr\rli bq, Uant [,ti]a s pada ,et,op jcorr rnolehul
po rt
''
E .,zor': J!.t-\ Urlle,,l und !P3s 1nc''
Re
U) Da{tu'. k'{al'a
Pou\* Y.., eorq
Uppn. saddle
'
Uonvers
r,,-,
Qi
's L
'{ $rutca,
Riue r
la
G.aw Chqng , R.) aoro ., Checo-i:tq'' -f' &n* aCI', e'vn. v 'r G ) lurrrvv ,J;^,; L,r{IltLIl -=!-\.,
,
M an de
;;;;f
Ti*bu.\ahe,
\A.l
UPPec
., 2ct rq' Dgt't
Sa
ddle
n
S Le*k, hn ge.oho n
l-lr\1, New Yor.Lt
Chetn'tt,.q
'
so
,\
r
fdanf,{rharr Songrro AlLohol
dan Ester
Ja
\o.,rr\ro. {a,
2\
AP,.'l eu's
^{J.
1.r*i,r[,han
Scme
',
't"g'J'l:lll; i:f:: Inc'r Peo"on Edu."a\ton
ko\,,h\,ruc,., t{rr,,, },so. Porooboo^ C-Z
Sori )
If,) Lo*Flron Loprron
Pearson Ed,lta{ton Jnc
Rive r
Mu*n+rh ui , Ar,s{rl. Pe*birbin3
(Andoni N\ila
']ohn
ab
Brodg ,]annes
Mondalq )
nlarq
